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Since the scanning tunneling microscope allows scientists to visualize regions of high electron density and hence infer the position of individual atoms and molecules on the surface of a lattice, STM nowadays has numerous applications in nanoscience, catalysis and surface science.§Here, top international authors in the field of STM and surface science present first-class contributions on this hot topic, bringing the reader up to date with the latest developments in this rapidly advancing field. The focus is on the nanoscale, particularly in relation to catalysis, involving developments in our understanding of the nature of the surfaces of oxides and nanoparticulate materials, as well as adsorption, and includes in-situ studies of catalysis on such model materials. §Of high interest to practitioners of surface science, nanoscience, STM and catalysis.